How can you distinguish between ethylamine and diethylamime

Dear Student

Ethylamine is primary amine that gives positive carbylamine test.

Ethylamine gives a foul odour when heated with chloroform and alcoholic KOH.

Diethylamine is secondary amine that does not give carbylaimne test.

Reaction for ethylamine is:

C2H5NH2 + CHCl3 + 3 NaOH → C2H5NC + 3 NaCl + 3 H2O

C2H5NC is foul smelling compound.

Regards

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