On dissolving a non volatile and non electrolyte solute in water the vapour pressure of water decreases to 740 mm hg. The molality of solution approximately will be

Dear Student,

At RT, Vapour pressure of water (P°)=760 mmHgVapour pressure on addition of solute (P)=740 mmHgWe know that,P°-PP° = x2where x2 is the mole fraction of soluteSo, x2 = 760-740760=20760=0.026Molality (m ) =1000x2x1M1where M1 is the molar mass of solventSolvent is water here so M1=18 gmol-1x1=1-0.026=0.974So, m =1000×0.0260.974×18=1.48 molal

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