why are metals sulphide and carbonate converted into metal oxide prior to reduction during the extraction of metals . explain by giving one example in each case
Conversion of concentrated ore into metal oxide
It is easier to obtain metals from their oxides rather than from carbonates or sulphides. So the ore is first converted into an oxide. A carbonate ore is first converted into oxide ore by calcination. A sulphide ore is converted into oxide ore by roasting.
1. Calcination process
It is the process of heating the concentrated ore at a temperature not sufficient to melt the ore. The water content and the volatile impurities also get expelled. Zinc carbonate in its ore calamine (ZnCO3) is calcinated to obtain zinc oxide (ZnO).
ZnCO3 | -------------> | ZnO | + | CO2 |
calcination |
2. Roasting process
It is the process of heating the concentrated ore in the presence of excess air. Volatile impurities also get expelled.
Zinc sulphide in its ore zinc blende ( ZnS) is roasted to obtain zinc oxide (ZnO).
2ZnS | + | 3O2 | -----> | 2ZnO | + | 2SO2 |
(from air) |
Mercuric oxide is obtained by roasting cinnabar (HgS) in air.
2ZnS | + | 3O2 | -----> | 2ZnO | + | 2SO2 |