Why is it generally preferable to use absorbance as a measure of absorption rather than % Transmittance?also explain.....

Options
  • A)

    Because %T is dependant on the power of the incident radiation

  • B)

    Because absorbance is proportional to the concentration of the analyte, whereas %T is not.

    C)

    Because %T cannot be measured as accurately as absorbance

  • D)

    None of these are correct

The correct answer is option B.

Because absorbance is directly proportional to the concentration of the analyte, whereas %T is not.

Absorbance is denoted as
A = Ɛ.b.c
where Ɛ = molar absorptivity
b= path length
c= concentration
thus there is a direct relation between A & c if Ɛ and b are constant.

whereas,
A = log10 1 /%T i.e. Ɛ.b.c = log10 1 /%T
thus the relation between conc, and %T is not direct and hence use of %T is not preferrable.

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