Why the third ionisation enthalpy of Mn is generally exceptionally high?
bcoj when Mn+2 oxidises to Mn+3.before oxidation it hav 3d5 4s0 ,it gains half filled configuration but after oxidation in Mn+3 state ,1 more electron have to be released so it releases from half filled configuration which is stable .so to remove third electon it results high ionisation enthalpy.