10g of a sample of conc. HCl was diluted with water and the  solution was added to  a piece of CaCO3 weighing 7g. After completion of the reaction, 2.8 g of marble remained unreacted. What was the percentage strength of the conc. acid?

CaCO3 + 2HCl CaCl2 + H2O +CO2100 g of CaCO3 reacts with 2 × 36.5 = 73 g of HClIts given 2.8 g of marble remains unreacted. That means all HCl is consumed and is the limiting reagentThe amount of marble reacted = 7 -2.8 = 4.2 gThe amount of HCl needed for 4.2 g of CaCO3 = 73100×4.2=3.066 gThe % strength = 3.06610 × 100 = 30.66 %

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