in a solvent 50% of benzoic acid dimerises while the rest ionises. determine molar mass of acid which is observed and also its van't hoff factor.
Your friend is correct.
Formula to calculate i ( Van't haff factor) using (degree of ionizaion) is as follows:
i = (1-) +
Here,
= 50/100 = 0.5
n = 2 (dimerisation)
i = (1.0-0.5) + 0.5/2
= 0.75
i =
0.75 =
Observed Molar mass = 0.75 x 122 g/mol
= 91.5 g/mol
Formula to calculate i ( Van't haff factor) using (degree of ionizaion) is as follows:
i = (1-) +
Here,
= 50/100 = 0.5
n = 2 (dimerisation)
i = (1.0-0.5) + 0.5/2
= 0.75
i =
0.75 =
Observed Molar mass = 0.75 x 122 g/mol
= 91.5 g/mol